Electrochemical and optical properties of a redox-active Cu(II) coordination framework incorporating the tris(4-(pyridin-4-yl)phenyl)amine ligand.
نویسندگان
چکیده
A new redox-active ligand, tris(4-(pyridin-4-yl)phenyl)amine (Npy3), has been synthesised, and incorporated into the coordination framework [Cu(Npy3)Cl2]·DMF. The monoradical cation of the ligand is readily accessible, thus enabling chemical oxidation of the framework. The novel Npy3 ligand has significant potential as a structural motif for the development of multifunctional frameworks.
منابع مشابه
Facile redox state manipulation in Cu(I) frameworks by utilisation of the redox-active tris(4-(pyridin-4-yl)phenyl)amine ligand.
The incorporation of a redox-active tris(4-(pyridine-4-yl)phenyl)amine (NPy3) ligand into the Cu(I) coordination frameworks [CuNPy3NO3·solvent]n and [CuNPy3Cl·solvent]n has been shown to facilitate redox state switching in the materials. In both cases, the initial Cu(II) metal centre was reduced in situ during the solvothermal synthesis under relatively mild conditions where the use of chloride...
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عنوان ژورنال:
- Dalton transactions
دوره 42 18 شماره
صفحات -
تاریخ انتشار 2013